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The thiol is deprotonated first, before reacting with H 2 O 2 , with the rate-determining transition state of the reaction being methanethiolate attack on H 2 O 2

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So even the topical route, which is the evidence-backed one, should be described as supported by small, sometimes industry-affiliated human cosmetic studies with modest effect sizes, not as proven. The correct posture toward topical GHK-Cu is cautious optimism grounded in real but imperfect human data which is still a materially stronger position than the injectable route can claim